With a point gained on the road eight days ago, it was time for the first league match of the season at Fir Park.
Hibernian made the journey down the M8 to North Lanarkshire, fresh off the back of an impressive Europa Conference League win against Luzern on Thursday night.
Dan Casey would go closest for the Steelmen in the first half, when his header came crashing off the bar just before half time.
Hibernian failed to register a shot on target until the 94th minute and Motherwell looked to make the most of it.
Arsenal loanee Mika Biereth came off the bench to make his debut and made his impact. He battled with Louis Stevenson before picking Conor Wilkinson, who opened the scoring on 66 minutes.
He continued to cause havoc upfront and doubled the ‘Well’s lead with five minutes to go.
Casey would be penalised for a handball in the area with seconds remaining as Hibernian got a consolation. There would be no comeback and Motherwell start the season with four points out of a possible six.